Things to consider when shooting sunsets...
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Remove your lens filters unless you specifically need a graduated neutral density filter.
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Clean your lens with a high quality lens cloth, such as Zeiss Wipes, or you will get nasty and spotting.
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Use a tripod and start planning your shot at least 30 minutes early.
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Use a small aperture, say f11.
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Expose for the brightest sky immediately surrounding the sun. The sun is king in sunset pics.
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Use a wide angle lens at f22 with the sun partially blocked to create a star effect.
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Give your subject the most room in the scene. If you are shooting the dramatic sky, fill the photo with mostly sky. If you are shooting a silhouette with your subject in the foreground, fill the photo with mostly foreground.
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Use fill flash for backlit, sunset portraits.
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Don't be afraid to shoot vertically.
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Bracket your exposures.
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Shoot constantly as the light will change every second.
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Keep shooting after the sun passes the horizon.
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Use live view instead of the viewfinder, it's easier on your eyes.
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Use aperture priority and auto ISO in rapidly changing lighting. You will need to use exposure compensation to fine tune the exposure first.
